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Liquid Magics Australia 
MATERIAL SAFETY DATA SHEET

Product Name: Citrus Cleaner
Page: 1 of 7

This revision issued : July 2018

Section 1 - Identification of Chemical Product and Company
Liquid Magics Australia - Phone : (02) 95701981
P O Box 143
Penshurst. NSW. 2222
Email: info@liquidmagics.com.au
Emergency Phone No. 0410 091 918
Substance: Principally Lactic Acid a registered anti-bacterial agent, Orange Oil and D-limonene based Multi-purpose cleaner / Spray and Wipe. 
Trade Name: Liquid Magics Citrus Cleaner
Product Code: LMCC
Product Use: Multi Purpose Cleaner
Creation Date: July, 2005
Revision Date: July 2018

Section 2 - Hazards Identification

Statement of Hazardous Nature 
This product is classified as: Hazardous according to the criteria of NOHSC Australia. 
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. 
Risk Phrases: R43. May cause sensitisation by skin contact. 
Safety Phrases: S25, S28. Avoid contact with eyes. After contact with skin, wash immediately with plenty of water. 
SUSDP Classification: None allocated. 
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. 
UN Number: None allocated

Emergency Overview

Physical Description & Colour: Clear colourless to slight orange, yellow liquid. 
Odour: Characteristic citrus fragrance. 
Major Health Hazards: skin irritant, possible skin sensitiser. 

Potential Health Effects

Note: sensitisation to ingredients such as d-limonene occurs in only a small percentage of persons, but those who are sensitised may show severe reactions. Most people may use this product in complete safety, however those sensitised to d-limonene should avoid contact with this product. 

Inhalation
Short Term Exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this product is not harmful. In addition product is unlikely to cause any discomfort or irritation. Long Term Exposure: No data for health effects associated with long term inhalation. 

Product Name: Citrus Cleaner
Page: 2 of 7
This revision issued : July 2018 

Skin Contact: 
Short Term Exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can be severe. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort. 

Long Term Exposure: No data for health effects associated with long term skin exposure. 

Eye Contact: 
Short Term Exposure: Exposure via eyes is considered to be unlikely. This product may cause eye irritation when present at high vapour pressures; for example when heated or in enclosed spaces. In addition product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort. 
Long Term Exposure: No data for health effects associated with long term eye exposure. 

Ingestion: 
Short Term Exposure: Significant oral exposure is considered to be unlikely. This product, while believed to be not harmful, is likely to cause headache and gastric disturbance such as nausea and vomiting if ingested in significant quantities. This product is unlikely to cause any irritation problems in the short or long term. 
Long Term Exposure: No data for health effects associated with long term ingestion. 

Carcinogen Status: 
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC. 
NTP: No significant ingredient is classified as carcinogenic by NTP. 
IARC: D-limonene is Class 3 - unclassifiable as to carcinogenicity to humans. 
See the IARC website for further details. A web address has not been provided as addresses frequently change. 

Section 3- First Aid Measures

General Information: 
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call. 
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. 
Skin Contact: Gently blot away excess liquid. Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until chemical is removed. 
Eye Contact: Quickly and gently blot material from eyes. Flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while holding the eyelid(s) open. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. 
Ingestion: If product is swallowed or gets in mouth, wash mouth with water and give some water to drink. 
If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor. 


Material Safety Data Sheet

Issued by: Liquid Magics Australia - Phone: (02) 9570 1981
Product Name: Citrus Cleaner
Page: 3 of 7
This revision issued : July 2018

Section 4 - Fire Fighting Measures


Fire and Explosion Hazards: This product is classified as flammable. There is a moderate risk of an explosion from this product if commercial quantities are involved in a fire. Fire fighters should take care and appropriate precautions. Any explosion will likely spread the fire to surrounding materials. Water spray may be used to cool drums involved in a fire, reducing the chances of an explosion. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back considerable distances. 

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures. Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam. Foam is the preferred medium for large fires. Ensure that no spillage enters drains or water courses. 

Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. 
Flash point: 52°C (Closed cup) 
Upper Flammability Limit: No data. 
Lower Flammability Limit: No data. 
Auto ignition temperature: No data. 
Flammability Class: Flammable


Section 5 - Accidental Release Measures

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate the spill area and deny entry to unnecessary and unprotected personnel. Immediately call the Fire Brigade. Wear full protective clothing including eye/face protection. All skin areas should be covered. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned below (section 8). 

Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Avoid using sawdust or other combustible material. Any electrical equipment should be non-sparking. Any equipment capable of building an electrostatic charge should be electrically grounded. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Can be slippery on floors, especially when 

wet. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry. 

Exothermic reactions leading to spontaneous combustion are possible when products of this type are absorbed onto porous materials such as zeolites, other mineral derived products, and even rags. Therefore, avoid the use of those materials and seek specialist advice in large scale cleanup processes. 

Material Safety Data Sheet

Issued by: Liquid Magics Australia - Phone: (02) 9570 1981
Product Name: Citrus Cleaner
Page: 4 of 7
This revision issued : July 2018


Section 6 - Handling and Storage

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10. 

Storage: Store in a cool, well ventilated area, and make sure that surrounding electrical devices and switches are suitable. Check containers periodically for leaks. Containers should be kept closed in order to minimise contamination and possible evaporation. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. If you keep more than 1000L of flammable liquids of Packaging Group III, you are probably required to license the premises or notify your Dangerous Goods authority. If you have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check packaging - there may be further storage instructions on the label. 

Section 7 - Exposure Controls and Personal Protection

The following Australian Standards will provide general advice regarding safety clothing and equipment: 
Respiratory equipment: AS/NZS 1715
Protective Gloves: AS 2161
Industrial Clothing: AS2919 
Industrial Eye Protection: AS1336 and AS/NZS 1337
Occupational Protective Footwear: AS/NZS2210
Exposure Limits: TWA (mg/m3) STEL (mg/m3) 
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product. 
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. 
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that vapours and mists are minimised. 
Eye Protection: Eye protection such as protective glasses or goggles should be worn when there is a chance of irritant levels of vapours being generated. However, it would be better to remove the vapours or avoid their generation. 
Skin Protection: If you believe you may have a sensitisation to this product or any of its declared ingredients, you should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin areas are covered. See below for suitable material types. 


Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. 
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above. 
Safety deluge showers should, if practical, be provided near to where this product is being used. 


Material Safety Data Sheet
Issued by: Liquid Magics Australia - Phone: (02) 9570 1981

Product Name: Citrus Cleaner
Page: 5 of 7
This revision issued : July 2018


Section 8 - Physical and Chemical Properties: 

Physical Description & colour: Clear colourless to slight orange, yellow liquid. 
Odour: Characteristic citrus fragrance. 
Boiling Point: 175°C at 100kPa
Freezing/Melting Point: -75°C
Volatiles: No specific data. Expected to be low at 100°C. 
Vapour Pressure: No data. 
Vapour Density: No data. 
Specific Gravity: 0.844
Water Solubility: Insoluble. 
PH: No data. 
Volatility: No data. 
Odour Threshold: No data. 
Evaporation Rate: No data. 
Coeff Oil/water Distribution: No data
Auto ignition temp: No data. 

Section 9 - Stability and Reactivity

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. 
See Section 6 of this MSDS regarding reactivity with porous materials and rags. 
Conditions to Avoid: This product should be kept in a cool place, preferably below 30°C. Keep away from sources of sparks or ignition. Handle and open containers carefully. 
Incompatibilities: oxidising agents, porous materials such as zeolites and similar mineral products, rags. 
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. 
Polymerisation: Polymerisation reactions are unlikely; they are not expected to occur. 


Section 10 - Toxicological Information

Local Effects: 
Target Organs: There is no data to hand indicating any particular target organs. 
D-limonene is Classed by NOHSC as a potential sensitiser by skin contact. 

Classification of Hazardous Ingredients

Ingredient Risk Phrases
D-limonene Conc>=20%: Xi; R38; R43

Material Safety Data Sheet

Issued by: Liquid Magics Australia - Phone: (02) 9570 1981
Product Name: Citrus Cleaner
Page: 6 of 7
This revision issued : July 2018

Section 11 - Ecological Information
Toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. Insufficient data to be sure of status. 

Section 12 - Disposal Considerations

Disposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containers either in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. Please do NOT dispose into sewers or waterways. 

Section 13 - Transport Information

ADG Code: 2319, TERPENE HYDROCARBONS, N.O.S. 
Hazchem Code: 3[Y] 
Special Provisions: SP109
Dangerous Goods Class: Class 3, Flammable liquids. 
Packaging Group: III
Packaging Method: 3.8.3, RT1

Class 3 Flammable Liquids shall not be loaded in the same vehicle or packed in the same freight container with Classes 1 (Explosives), 2.1 (Flammable Gases where flammable liquids and flammable gases are both in bulk), 2.3 (Toxic Gases), 4.2 (Spontaneously Combustible Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6 (Toxic Substances, except Flammable Liquid is nitromethane), and 7 (Radioactive Substances). They may however be loaded in the same vehicle or packed in the same freight container with Classes 2.1 (Flammable Gases except where the Flammable Liquids and Flammable Gases are in bulk), 2.2 (Non-Flammable Non-Toxic Gases), 4.1 (Flammable Solids), 4.3 (Dangerous When Wet Substances), 6 (Toxic Substances, except where Flammable Liquid is nitromethane), 8 (Corrosive Substances), 9 (Miscellaneous Dangerous Goods), Foodstuffs or foodstuff empties. 


Section 14 - Regulatory Information

AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database. 

Material Safety Data Sheet

Issued by: Liquid Magics Australia - Phone: (02) 9570 1981

Product Name: Citrus Cleaner
Page: 7 of 7
This revision issued : July 2018

Section 15 - Other Information

This MSDS contains only safety-related information. For other data see product literature. 

Acronyms: 
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS Number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially fire fighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NOS Not otherwise specified
NTP National Toxicology Program (USA) 
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number

THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS

OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST. 

Please read all labels carefully before using product. This MSDS is prepared in accord with the NOHSC document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] 

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